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    Present development and prospect of RH vacuum refining
    Steelmaking    2025, 41 (1): 1-11.  
    Abstract724)      PDF(pc) (1360KB)(343)       Save
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    Control process of oxide inclusions in ultralow carbon IF steel
    Steelmaking    2024, 40 (6): 75-82.  
    Abstract118)      PDF(pc) (3402KB)(235)       Save
    In order to improve the castability and cleanliness of ultra-low carbon IF steel in continuous casting, the optimization of converter bottom blowing process, carbon and oxygen contents control at the endpoint, top slag modification, efficient vacuum deeper decarburization technology and enhancing protection of casting process were carried out. The results showed that using the annular-tubes type bottom nozzle instead of the original capillary type gas permeable brick bottom blowing, the single tube bottom blowing intensity 0.086 m3/(t·min), and the stirring energy 0.40 W/t, which could significantly improve the stirring capacity in the later stage of blowing. The average carbon and oxygen product of the molten steel at the endpoint of the converter reached 0.002 09. The vacuum was rapidly pumped to the limit vacuum degree, and the vacuum decarburization efficiency was the highest at 3-5 min forced oxygen blowing stage and holding 8-12 min under limit vacuum degree. Reducing the residual oxygen content after vacuum decarburization and optimizing the top slag composition of ladle could significantly reduce the Al2O3 inclusion formation and promote the adsorption and dissolution of inclusions by top slag. With the protection of continuous casting,the control level of oxide inclusion and pouring ability of molten steel has been significantly improved.
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    Dual functions and control methods of MnS inclusions in non-quenched and tempered steel
    Steelmaking    2025, 41 (3): 19-.  
    Abstract115)      PDF(pc) (4142KB)(203)       Save
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    Physical simulation and industrial testing of the interaction between oxygen lance and molten pool in a 210 t converter
    Steelmaking    2025, 41 (2): 30-37.  
    Abstract142)      PDF(pc) (1174KB)(230)       Save
    To solve the problems of low oxygen supply intensity and long smelting cycle in the 210 t large converter, 10 oxygen lance nozzles were designed and water model test were performed. The results showed that the impact cavity formed by the 5-hole oxygen lance jet had better independence, and under the same oxygen flow rate, its impact depth was greater than that of the 6-hole oxygen lance. Among the ten oxygen lance nozzles, the nozzle 3 and nozzle 4 have the best impact depth. The impact area (radius) significantly increases with the increase of inclination angle, and the nozzle 3, 4, 9 and 10 have better impact areas compared with other nozzles. Therefore, the nozzle 3 was used as the new 5-hole oxygen lance for industrial testing, and the nozzle 9 was used as the new 6-hole oxygen lance for industrial testing. The experimental results were compared with the original 6-hole oxygen lance. The industrial test results show that in terms of phosphorus removal ability, the new 6-hole lance is the best, while the original 6-hole lance is the worst. Compared to the original 6-hole lance, the new 5-hole lance does not have the ability to shorten the oxygen supply time, while the average oxygen supply time of the new 6-hole lance is shortened by 22 s. In terms of lifespan, the new 5-hole lance is not as good as the original 6-hole lance, while the lifespan of the new 6-hole lance is equivalent to that of the original 6-hole lance.Compared to the original 6-hole lance, the new 6hole lance has a significant effect on reducing the total iron content in slag and steel material consumption.
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    Effect of deoxidation and alloying process for the cleanliness of Al-killed steel
    Steelmaking    2025, 41 (1): 53-62.  
    Abstract299)      PDF(pc) (2103KB)(212)       Save
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    Gasification characteristics and exergy analysis on pulverized coal-CO2 in wet flue gas of 120 t converter
    Steelmaking    2025, 41 (4): 90-96.  
    Abstract89)      PDF(pc) (1395KB)(146)       Save
    In order to make the converter vaporizing flue blowing pulverized coal process applied to iron and steel production with low cost and high applicability, and to achieve the purpose of carbon reduction, it is necessary to study the reaction characteristics of pulverized coal gasification-conversion reaction with CO2 in high temperature flue gas of converter as well as to conduct the exergy. The reaction characteristics of pulverized C-CO2 under different atmospheric and temperature conditions were investigated by settling furnace experiments, and industrial tests were carried out in a 120 t converter wet flue gas system, the change in exergy loss and exergy efficiency was calculated during the test.The results of the settling furnace experiments showed that the higher the reaction temperature was, the more favorable the reaction of pulverized C-CO2 was, and it reached the maximum at 1 350 ℃; with the increase of CO2∶CO ratio in the atmosphere, the conversion of CO2 in the flue gas showed an increasing trend.The results of the industrial experiments showed that, in the case of pulverized coal blowing amount of 3.76 kg/t, the average volume fraction of CO in the converter gas increased by 5.53 percentage points, the average volume fraction of CO2 decreased by 3.83 percentage points, and the value of the recovered gas increased by 2 690.95 kJ/m3.And with the increase of coal injection, the exergy efficiency increased by 89.06% which showed that it was feasible to convert CO2 into CO by blowing pulverized coal in the converter vaporizing flue, and the pulverized coal-CO2 gasification reaction was well.
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    Numerical simulation and application research on the secondary combustion oxygen lance nozzle of a 100 t converter
    Steelmaking    2025, 41 (2): 16-23.  
    Abstract124)      PDF(pc) (3318KB)(183)       Save
    Based on the oxygen supply parameters of a 100 t converter, a secondary combustion oxygen lance nozzle was designed and the turbulent jet characteristics of the fluid inside the converter were described through  k-ε  model calculation. A secondary combustion oxygen lance nozzle with a diameter of 13.3 mm, a tilt angle of  38°, and 8 secondary holes was design. The nozzle was applied in industrial production under the condition of oxygen flow rate of  24 500-26 000 m3/h and working oxygen pressure of 0.85 MPa. Industrial tests showed that the secondary combustion oxygen lance nozzle could meet the normal requirements for converter slagging. Compared to conventional oxygen lance nozzles, the secondary combustion oxygen lance nozzle had better smelting effect at the upper limit of oxygen flow rate of 26 000 m3/h, which was beneficial for controlling converter splashing and slag overflow. The secondary combustion oxygen lance nozzle could exert the secondary combustion effect of CO in the furnace, increase the temperature of molten steel by 23.80 ℃, increase the scrap ratio by 1.48%, and achieve good application results.
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    Numerical simulation study on bottom powder injection in RH refining process
    Steelmaking    2024, 40 (1): 39-46.  
    Abstract190)      PDF(pc) (1656KB)(226)       Save
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    New research progress on the resource utilization of steelmaking slag in Japan
    Steelmaking    2025, 41 (5): 1-10.  
    Abstract96)      PDF(pc) (2380KB)(124)       Save
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    Optimization of flow control device in slab continuous casting tundishusing physical and mathematical simulations
    Steelmaking    2022, 38 (6): 29-37.  
    Abstract226)      PDF(pc) (1739KB)(158)       Save
    In order to optimize the flow pattern of molten steel in the continuous casting tundish to effectively remove nonmetallic inclusions,a multi-hole flow control device with different apertures was proposed in this study.A 1∶4 hydraulics model experiment was conducted to simulate a 70 t two-strand slab continuous casting tundish to measure RTD curves and a three-dimensional numerical model was established to analyze the flow field. The effects of the casting speed and the installation position of the flow control device on the flow characteristics of the molten steel in the tundish were studied,and the optimal combination of flow control devices was obtained. The results show that the flow rate is improved, the path of the fluid flow can be prolonged, the average resistance time is prolonged and the dead zone volume fraction is decreased. The flow control device of Sf=4 has the best effect on improving the flow field when the distance between the flow control device and the weir is 150 mm, and when the casting speed is 1.0,1.2,1.4 m/min,the dead zone volume fraction decreases 17.42 %, 15.55 %,28.72 %,the peak time is prolonged by 75, 41,56 s, the average residence time is prolonged by 78, 87, 126 s, respectively. 
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    Research progress on several key technologies of converter steelmaking 
    Steelmaking    2024, 40 (1): 1-8 .  
    Abstract459)      PDF(pc) (1984KB)(327)       Save
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    Characteristics and judgment method of liquid slag layer thickness in mold measured by copper-coated steel wire
    Steelmaking    2025, 41 (4): 59-65.  
    Abstract150)      PDF(pc) (4329KB)(110)       Save
    Currently, steel plants mainly use copper-coated steel wire to measure the thickness of the liquid slag layer in the mold, but this method lacks standardized judgment criteria and accurate evaluation. In this study, a high-frequency induction furnace was used to simulate the mold's thermal environment, and copper-coated steel wire was employed to measure slag layer thickness. The post-measurement characteristics of the copper-coated steel wire were analyzed by SEM-EDS. Then, its formation mechanism was analyzed, and the judgment method was optimized. The results show that the powder layer and the upper part of the sintering layer do not reach the copper melting point (1 083 ℃) with no obvious change on the surface of the copper-coated steel wire. The temperature of the lower part of the sintering layer is over 1 083 ℃, after the copper melts, the exposed steel wire oxidizes to black. As the liquid slag layer heats up, the wire gets immersed and turns bright white. This parts not fully covered oxidize slightly, appearing grey. The length of the grey and white sections indicates the slag layer's thickness. This judgment method has been verified in the continuous casting site, but its accuracy is not as good as double-wire wetting method. 
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    Application and carbon emission analysis of CO2 top-bottom combined blowing process in 210 t converter
    Steelmaking    2025, 41 (6): 23-29.  
    Abstract95)      PDF(pc) (1155KB)(109)       Save
    Based on the actual experimental data of a 210 t converter in a steel enterprise in Shandong Province, the impact of introducing CO2 into the converter steelmaking process on smelting performance and carbon emissions was explored. The results indicate that the CO2 injection process can effectively improve the dephosphorization rate of the converter, reduce the end-point carbon oxygen product, increase the recovery and calorific value of the converter gas, and significantly optimize the resource utilization efficiency. And it effectively reduces the generation of solid waste. In terms of carbon reduction, compared with conventional processes, the converter CO2 top and bottom combined blowing process reduces the carbon emissions per ton of steel by 8.5% to 11.6%. The CO2 top and bottom combined blowing steelmaking process not only improved smelting efficiency and economic benefits, but also had significant advantages in low-carbon transformation, providing an effective path for the steel industry to achieve green development.
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    Development and prospect of carbonization treatment of BOF slag
    Steelmaking    2025, 41 (4): 1-9.  
    Abstract313)      PDF(pc) (1548KB)(102)       Save
    Two types of direct carbonization methods of BOF slag, and their influencing factors and kinetics mechanism were summarized. The possible rate-limiting step for hotstage carbonation treatment of slag is the diffusion of CO2 through the product layer to the unreacted zone inside the particle. The increase of temperature can accelerate the diffusion rate of CO2, and the decrease of particle size of slag can reduce the thickness of product layer that inhibits the diffusion, thus which can contribute to enhancement of CO2 sequestration and improvement of conversion rate during hot-stage carbonation treatment of slag. The main controlling step for aqueous carbonation treatment is the diffusion of calcium from the inside to the surface of steel slag. Reducing the particle size of steel slag and destroying the product layer by ultrasonic vibration are the most effective ways to accelerate the diffusion leaching of calcium. Due to the high temperature of steel slag from the converter, and both carbonization methods have some limitations, it is considerable to combine the two ways. The slag with high temperature is carbonized by hot-stage carbonation treatment at elevated temperature during cooling. By reducing the particle size of steel slag and increasing the CO2 pressure, the CO2 sequestration and calcium conversion rate are improved. Fixing a part of calcium through hot-stage carbonation and then performing aqueous carbonation is beneficial for shortening the aqueous carbonation time. After the steel slag is cooled and continued to be milled, aqueous carbonation treatment is carried out. Combined with size optimization and ultrasonic utilization, the steel slag can be carbonized to the maximum extent, which is more promising for energy save and emission reduction.
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    Prediction model of phosphorus content in converter steelmaking based on  ensemble learning
    Steelmaking    2025, 41 (2): 9-15.  
    Abstract199)      PDF(pc) (1550KB)(146)       Save
    Accurate prediction of endpoint phosphorus content can solve the problem that the composition of molten steel cannot be continuously detected during the converter blowing process, promote the rapid tapping of the converter and shorten the smelting cycle.Based on the actual production data of a 100 t converter in a steel mill in Hunan Province, a prediction model of molten steel phosphorus content at the end of the converter based on an ensemble learning algorithm was established. The main influencing factors were determined by analyzing the converter dephosphorization process, and the input variables of the model were determined based on the actual production of the steel mill. The interquartile range method, LOF algorithm and other methods were used for data preprocessing, and the best parameters of the model were determined by combining the 10-fold cross validation method and the grid search method.Four ensemble learning algorithms (RF, AdaBoost, MultiBoosting, and Stacking) were used to establish the models, and  the prediction results of the four models were compared, it was found that the Stacking model had the best prediction effect, with the highest hit rate, the lowest root mean square error and the average absolute percentage error, and the hit rates were 86.08% and 97.84% when the error of molten steel phosphorus mass fraction at the prediction end point was ±0.003% and ±0.005%, respectively.
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    Research progress on mechanism of submerged entry nozzle clogging in continuous casting
    Steelmaking    2025, 41 (6): 1-9.  
    Abstract81)      PDF(pc) (1569KB)(99)       Save
    Nozzle clogging is a prevalent issue in continuous casting. It not only disrupts casting stability but escalates into nozzle blockage in severe case, resulting in decreased production efficiency and slab quality deterioration. The composition and structure of clogging deposits for typical steel grades were summarized. The mechanisms of submerged entry nozzle clogging were reviewed from three aspects: the physical adhesion of inclusions, chemical reactions in steel-refractory system, and the temperature drop resulted from the insufficient preheating.Chemical reactions were emphasized, including decarburization reactions, interactions between molten steel and refractory, and reoxidation reactions. Additionally,the discussion extended to numerical simulation studies in regard to nozzle clogging, mainly including flow field simulations and model of inclusion motion. Finally, the prevention strategies against nozzle clogging were discussed: the cleanliness improvement of steel, the argon blowing technique,the optimization of SEN parameters, and the external electric field and magnetic field treatment.
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    Optimization and industrial testing of refining slag system for silicon killed steel Q235B
    Steelmaking    2024, 40 (6): 32-40.  
    Abstract115)      PDF(pc) (2962KB)(130)       Save
    In order to improve the cleanliness of silicon-killed steel Q235B and find a suitable refining slag system, thermodynamic calculations and laboratory experiments were carried out to determine the appropriate composition of refining slag and reduce the basicity of the original process slag system.The basicity of the optimized slag system was controlled between 1.70 and 2.0, and the mass fraction of Al2O3 was controlled between 7.0% and 10.0%. The optimized slag system were successfully used in industrial tests.The results showed that after optimizing the slag system, the mass fraction of T.O in Q235B silicon killed steel after LF refining in the industrial test furnace could be reduced to 42×10-6 on average, with a minimum of 26×10-6.The average mass fraction of  T.O in the slab can be reduced to less than 35×10-6. The maximum diameter of the inclusions in the tundish can be controlled below 20 μm,the number density of inclusions in the rolled material can be controlled below 15/mm2, and the area fraction of inclusions in the rolled material can be controlled below  35×10-6. The grade of inclusions in steel was significantly reduced and the cleanliness of molten steel was improved.
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