电工钢 ›› 2026, Vol. 8 ›› Issue (2): 20-27.

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取向硅钢表面涂层附着性研究进展

曾剑,王雄奎,程迪夫

  

  1.  (武汉钢铁有限公司硅钢部,湖北武汉 430083)

  • 出版日期:2026-04-28 发布日期:2026-04-29

Research progress on surface coating adhesion of grain‑oriented silicon steel

ZENG Jian, WANG Xiongkui, CHENG Difu

  

  1.  (Silicon Steel Division, Wuhan Iron and Steel Co. Ltd., Wuhan 430083, China)

  • Online:2026-04-28 Published:2026-04-29

摘要:

取向硅钢片表面的玻璃膜与无机绝缘涂层双层结构,是保障变压器铁心绝缘电阻、降低功率损耗、提升加工及耐蚀性能的关键。涂层与基体的紧密附着是实现上述性能的核心前提。本文从物理机制(机械锚固、润湿、弱边界层理论)和化学机制(化学键合、酸碱理论)两个维度阐释涂层附着原理,系统分析玻璃膜质量、表面清洗效果、涂液浸润性、化学键合作用等因素对涂层附着性的影响规律,并梳理取向硅钢附着性检测标准及装置的发展现状。研究表明,制备高质量玻璃膜、优化涂液组分与胶体二氧化硅尺寸形貌、提高表面清洗质量,是获得优异涂层附着性能的关键。最后指出,亟待制定上下游行业共同认可的取向硅钢附着性检测国际标准。

关键词:

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取向硅钢;涂层附着性;玻璃膜;无机绝缘涂层

Abstract:

The two‑layer structure composed of a glass film and an inorganic insulating coating on the surface of grain‑oriented silicon steel sheets is the key to ensuring the insulation resistance of transformer cores, reducing power loss, and improving processability and corrosion resistance. Tight adhesion between the coating and the substrate is the core prerequisite for achieving the above properties. In this paper, the coating adhesion mechanism is explained from two dimensions: physical mechanisms (mechanical interlocking, wetting, and weak boundary layer theories) and chemical mechanisms (chemical bonding and acid‑base theories). The influencing laws of glass film quality, surface cleaning effect, coating solution wettability, chemical bonding effect and other factors on coating adhesion are systematically analyzed, and the development status of testing standards and devices for the adhesion of grain‑oriented silicon steel is summarized. The results show that preparing high‑quality glass films, optimizing coating solution components and the size and morphology of colloidal silica, and improving surface cleaning quality are the keys to obtaining excellent coating adhesion performance. Finally, it is pointed out that there is an urgent need to formulate an internationally recognized testing standard for the adhesion of grain‑oriented silicon steel that is accepted by both upstream and downstream industries. 

Key words: grain?oriented silicon steel, coating adhesion, glass film, inorganic insulating coating