Steelmaking ›› 2022, Vol. 38 ›› Issue (6): 58-65.
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Abstract: The formation mechanism and evolution of inclusions in SAE8620RH gear steel produced by EAF→LF→VD→CC process in a domestic steel mill were studied by SEM-EDS and thermodynamic calculation. The results show that the oxygen-sulfur composite inclusions in steel mainly exist in the composite form of MgO·Al2O3 as the core and CaS wrapped outside. The experimental results show that the inclusions in liquid steel at the early stage of LF refining are mainly MgO·Al2O3, with a small amount of CaS wrapped around the outside. After Ca treatment, part of MgO·Al2O3 is modified into liquid calcium aluminate. After VD vacuum treatment, the CaS proportion of MgO·Al2O3 coating increased obviously. MgO·Al2O3 in the billet precipitates MnS again, forms a composite form of MgO·Al2O3-(Ca,Mn)S. Thermodynamic calculation results show that MgO·Al2O3 can be generated when the mass fraction of Al in liquid steel is 0.03 % and the mass fraction of Mg is 1.85×10-6. In the early stage of LF refining, CaS is mainly generated by the direct reaction of [S] and [Ca], while in VD vacuum process, [S] and [Ca] in liquid steel will further reacted to form CaS, and calcium aluminate outside MgO·Al2O3 will also reacted with [S] to form CaS.
Key words: SAE8620RH gear steel, inclusions, formation mechanism, evolution mechanism
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URL: http://www.bwjournal.com/lg/EN/
http://www.bwjournal.com/lg/EN/Y2022/V38/I6/58