电工钢 ›› 2025, Vol. 7 ›› Issue (4): 20-.

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低温加热取向硅钢热轧过程第二相沉淀析出的动力学计算

吴永春1,郭  琪2,贾志伟2,邵媛媛1   

  1. 1. 辽宁科技大学,辽宁 鞍山 114051; 2. 鞍钢集团股份公司冷轧硅钢事业部,辽宁 鞍山 114009
  • 出版日期:2025-08-28 发布日期:2025-09-01

Kinetic calculation of secondary phase precipitation in low temperature grain oriented silicon steel during hot rolling

WU Yongchun1, GUO Qi2, JIA Zhiwei2, SHAO Yuanyuan1   

  1. 1. University of Science and Technology Liaoning, Anshan 114051, China;  2. Ansteel Company Limited ColdRolling Silicon Steel Business Unit, Anshan 114009, China
  • Online:2025-08-28 Published:2025-09-01

摘要: 以低温加热取向硅钢为研究对象,利用热力学和动力学相关理论计算分析了热轧过程不同加热温度下MnS和AlN沉淀析出的动力学行为。结果表明,位错形核时的临界形核尺寸最小。均匀形核及位错形核机制下,AlN优先析出;晶界形核时,MnS优先析出。MnS的主要形核方式是晶界形核。AlN在温度低于1 323 K时的主要形核方式是位错形核。热轧过程中,温度高于1 425 K时,AlN在晶界形核析出时间最短,反之则以位错析出时间最短。温度高于1 450 K时,MnS在晶界形核析出时间最短,反之则以位错析出时间最短。在板坯出炉后AlN和MnS主要以晶界析出为主,粗轧后随着变形量增大、位错密度升高,有利于促进抑制剂沿位错析出

关键词: 取向硅钢, AlN, MnS, 形核机制, 析出

Abstract: ]Kinetics behavior of MnS and AlN particles nucleation precipitation in low temperature grain oriented silicon steel at different heating temperatures during hot rolling was calculated and analyzed by using thermodynamics and kinetics interrelated theory.The results showed that the critical nucleation size of dislocation nucleation is the smallest. AlN particles are nucleated preferentially under the homogeneous nucleation and dislocation nucleation mechanisms, while the MnS particles are nucleated preferentially under the grain boundary nucleation mechanism. The main nucleation mechanism of MnS particles is grain boundary nucleation. The main nucleation mechanism of AlN particles is dislocation nucleation at the temperature below 1 323 K. During the hot rolling process, the precipitation time of AlN particles is the shortest at grain boundary when the temperature is higher than 1 425 K, while it is the shortest at dislocation when the temperature is below 1 425 K. The precipitation behavior of MnS particles is consistent with that of AlN particles, but the corresponding temperature is 1 450 K. After the slab is rolled out, AlN and MnS mainly precipitate at grain boundaries. After the rough rolling process, with the increase of deformation amount and the rise of dislocation density, it is conducive to the precipitation of inhibitors along dislocations.

Key words: grain oriented silicon steel, AlN, MnS, nucleation mechanism, precipitation