电工钢 ›› 2026, Vol. 8 ›› Issue (3): 31-.

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无取向硅钢高温氧化过程研究

郭立合1,林泰安2,宋大伟1,李振忠1   

  1. 1.本钢北营轧钢厂,辽宁 本溪 117000;2.吉林建龙钢铁公司,吉林 吉林 132000
  • 出版日期:2026-06-28 发布日期:2026-06-18

Study on the high⁃temperature oxidation process of non⁃oriented silicon steel

GUO Lihe1,LIN Taian2,SONG Dawei1,LI Zhenzhong1   

  1. 1. Benxi Iron and Steel Beiying Steel Rolling Plant, Benxi 117000,China;
    2. Jilin Jianlong Steel Company,Jilin 132000,China
  • Online:2026-06-28 Published:2026-06-18

摘要: 为优化工业生产中无取向硅钢高温氧化控制及除鳞工艺,以低牌号工业用BW1300热轧无取向硅钢为研究对象,通过物理化学分析明确其合金成分,采用扫描电镜(SEM)、电子探针(EPMA)、X射线衍射仪(XRD)等表征手段,系统研究高温氧化过程中氧化铁皮厚度、相组成演变及不同加热制度对氧化铁皮结构的影响,重点分析合金元素作用及氧化机理。结果表明:1 150~1 177 ℃时,氧化铁皮与基体结合力较低,易于除鳞,与现有研究中温度影响氧化层附着力的结论一致;温度超过1 177 ℃时,Fe2SiO4与FeO形成共晶液相,导致氧化铁皮快速增厚、结构疏松。本研究补充了工业用BW1300硅钢的具体氧化特性,丰富了无取向硅钢高温氧化研究体系,其结论贴近工业生产实际,为除鳞工艺优化及氧化缺陷控制提供了理论依据与技术支撑。

关键词: 热轧无取向硅钢, 高温氧化, 氧化铁皮, 合金元素, 除鳞

Abstract: To optimize the high⁃temperature oxidation control and scale removal process of non⁃oriented silicon steel in industrial production, low⁃grade industrial BW1300 hot⁃rolled non⁃oriented silicon steel was selected as the research subject. Through physicochemical analysis, its alloy composition was determined, and characterization methods such as scanning electron microscopy (SEM), electron probe microanalysis (EPMA), and X⁃ray diffraction (XRD) were used to systematically study the thickness of oxidation scales, phase composition evolution, and the effects of different heating regimes on the structure of oxidation scales during high⁃temperature oxidation, with a focus on analyzing the role of alloying elements and oxidation mechanisms. The results show that at 1 150~1 177 ℃, the bonding force between the oxide scale and the substrate is relatively low, making it easy to remove the scale, which is consistent with previous studies on the effect of temperature on oxidation layer adhesion. When the temperature exceeds 1 177 ℃, Fe2SiO4 and FeO form a eutectic liquid phase, leading to rapid thickening and a loose structure of the oxide scale. This study supplements the specific oxidation characteristics of industrial BW1300 silicon steel, enriches the research system of high⁃temperature oxidation of non⁃oriented silicon steel, and its conclusions are close to industrial production practices, providing a theoretical basis and technical support for the optimization of scale removal processes and the control of oxidation defects.

Key words: hot?rolled non?oriented silicon steel, high?temperature oxidation, scale, alloy elements, descale