炼钢 ›› 2026, Vol. 42 ›› Issue (5): 68-75.

• 凝固与浇铸 • 上一篇    下一篇

Fe-Mn-C系高锰钢连铸保护渣成分及性能变化分析

富志生,俞越山,陈兴润   

  1. 甘肃酒钢集团宏兴钢铁股份有限公司,甘肃 嘉峪关 735100
  • 出版日期:2026-09-28 发布日期:2026-09-28

Analysis of composition and property changes of Fe-Mn-C high manganese steel continuous casting mold slag

FU Zhisheng, YU Yueshan, CHEN Xinrun   

  1. Hongxing Co., Ltd., Gansu Jiuquan Iron and Steel Group, Jiayuguan 735100, China
  • Online:2026-09-28 Published:2026-09-28

摘要: 高锰钢连铸生产中,钢水与保护渣之间的氧化还原反应导致保护渣发生成分变化,MnO浸入会促使保护渣性能变化,使得连铸工艺极不稳定。为提高连铸工艺生产高锰钢连浇炉数、改善连铸坯表面质量,结合国内外研究学者前期研究工作,阐述了Fe-Mn-C高锰耐磨钢Mn13化学成分、凝固特性以及渣-钢反应特点,通过实验室模拟以及理论分析,研究了连铸保护渣MnO的反应行为及稳定性。试验表明:对于Fe-Mn-C系高锰钢采用CaO-SiO?基保护渣,随着渣-钢反应进行,渣中SiO?含量降低而MnO含量迅速升高,钢中Si含量升高而Mn含量降低,初始MnO的配入量在保护渣中并无阻止反应的作用;随着保护渣中MnO含量提高,保护渣的黏度和转折温度逐渐降低,较低的转折温度延长了液态渣膜的存在时间,起到改善结晶器与铸坯间的润滑作用。研究结果可为Fe-Mn-C系高锰钢连铸生产提供重要的技术支撑。

关键词: 连铸;保护渣;Mn13钢;MnO;黏度;转折温度;结晶温度

Abstract: In the continuous casting process of high-manganese steel, the redox reactions between molten steel and mold slag induce compositional changes in the slag. The infiltration of MnO further drives changes in the slag's properties, rendering the continuous casting process highly unstable. To enhance the sequence casting heats of high-manganese steel and improve the surface quality of continuous casting slabs, this study elaborates on the chemical composition, solidification characteristics, and slag-steel reaction behaviors of the Fe-Mn-C high-manganese wear-resistant steel Mn13, drawing upon the prior research efforts of domestic and international scholars. Through laboratory simulations and theoretical analyses, the reaction behavior and stability of MnO in continuous casting mold slag were investigated. Experimental results indicate that for Fe-Mn-C high-manganese steel utilizing CaO-SiO?-based mold slag, as the slag-steel reaction proceeds, the SiO? content in the slag decreases while the MnO content rises rapidly; concurrently, the Si content in the steel increases whereas the Mn content declines. Notably, the initial dosage of MnO incorporated into the mold slag exhibits no inhibitory effect on the reaction. As the MnO content in the slag gradually increases during the reaction, both the viscosity and break temperature of the slag decrease progressively. The reduced break temperature extends the duration of the liquid slag film, thereby improving the lubrication between the mold and the cast slab. These findings can provide crucial technical support for the continuous casting production of Fe-Mn-C high-manganese steel.

Key words: continuous casting; mold slag; Mn13 steel; MnO; viscosity; break temperature; crystallization temperature