炼钢 ›› 2025, Vol. 41 ›› Issue (4): 90-96.

• 节能环保 • 上一篇    

120 t转炉湿法煤气回收煤粉-CO2气化特性及㶲分析

彭灿锋1,2,李  超2,涂智阳2,王  怡2,周建安2   

  1. 1.阳春新钢铁有限责任公司,广东 阳春 529600;
    2.武汉科技大学先进耐火材料全国重点实验室,湖北 武汉 430081
  • 出版日期:2025-08-05 发布日期:2025-07-31

Gasification characteristics and exergy analysis on pulverized coal-CO2 in wet flue gas of 120 t converter

  • Online:2025-08-05 Published:2025-07-31

摘要: 为了使转炉汽化烟道喷吹煤粉工艺低成本、高适用性地应用于钢铁生产,达到降碳的目的,需要研究煤粉在转炉高温烟气中与CO2的气化转化反应特性以及进行分析。通过沉降炉试验探究了不同气氛和温度条件下C-CO2的反应特性,在120 t转炉湿法煤气回收系统进行工业试验,并计算了试验过程中的损失和效率。沉降炉试验结果表明反应温度越高越有利于C-CO2反应,在1 350 ℃时达到最大;随着气氛中φ(CO2)/φ(CO)增大,烟气中的CO2转化量呈增加趋势。工业试验结果表明,在煤粉喷吹量为3.76 kg/t时,转炉煤气中φ(CO)增加了5.53百分点,φ(CO2)减少了3.83百分点,回收煤气的热值增加了2 690.95 kJ/m3,且随着喷煤量增加,效率增加到89.06%,结果表明在转炉汽化烟道内喷吹煤粉来将CO2转化为CO是可行的,煤粉-CO2气化反应情况良好。

关键词: 转炉, CO2转化, 转炉湿法除尘, ?损失, ?效率

Abstract: In order to make the converter vaporizing flue blowing pulverized coal process applied to iron and steel production with low cost and high applicability, and to achieve the purpose of carbon reduction, it is necessary to study the reaction characteristics of pulverized coal gasification-conversion reaction with CO2 in high temperature flue gas of converter as well as to conduct the exergy. The reaction characteristics of pulverized C-CO2 under different atmospheric and temperature conditions were investigated by settling furnace experiments, and industrial tests were carried out in a 120 t converter wet flue gas system, the change in exergy loss and exergy efficiency was calculated during the test.The results of the settling furnace experiments showed that the higher the reaction temperature was, the more favorable the reaction of pulverized C-CO2 was, and it reached the maximum at 1 350 ℃; with the increase of CO2∶CO ratio in the atmosphere, the conversion of CO2 in the flue gas showed an increasing trend.The results of the industrial experiments showed that, in the case of pulverized coal blowing amount of 3.76 kg/t, the average volume fraction of CO in the converter gas increased by 5.53 percentage points, the average volume fraction of CO2 decreased by 3.83 percentage points, and the value of the recovered gas increased by 2 690.95 kJ/m3.And with the increase of coal injection, the exergy efficiency increased by 89.06% which showed that it was feasible to convert CO2 into CO by blowing pulverized coal in the converter vaporizing flue, and the pulverized coal-CO2 gasification reaction was well.

Key words: converter, CO2 conversion, wet dedusting in converter, exergy loss, exergy efficiency