炼钢 ›› 2025, Vol. 41 ›› Issue (4): 84-89.

• 节能环保 • 上一篇    下一篇

CeO2和La2O3对炼钢用低碳镁碳砖性能影响研究

张  鑫1,2,3,卢  堃1,2,3,朱家兴1,2,3,刘  爽1,2,3,彭  军1,2,3,安胜利1,2,3   

  1. 1.内蒙古科技大学 稀土产业学院,内蒙古 包头 014000;
    2.内蒙古自治区先进陶瓷材料与器件重点实验室(内蒙古科技大学),内蒙古 包头 014010;
    3.教育部轻稀土资源绿色提取与高效利用重点实验室(内蒙古科技大学),内蒙古 包头 014010
  • 出版日期:2025-08-05 发布日期:2025-07-31

Study on the influence of CeO2 and La2O3 on the properties of low carbon magnesia carbon brick for steelmaking

  • Online:2025-08-05 Published:2025-07-31

摘要: 研究了添加稀土CeO2、La2O3对低碳镁碳砖强度及抗渣侵蚀能力的差异化影响。添加稀土CeO2后,低碳镁碳砖的显气孔率减小,体积密度、常温耐压强度增大,抗渣侵蚀性能有改善。添加CeO2后低碳镁碳砖更加致密,体积密度由3.00 g/cm3增加至3.04 g/cm3,显气孔率由3.57%降低到3.16%。随着稀土CeO2的加入,低碳镁碳砖的强度亦上升,抗压强度由34.7 MPa增加至41.3 MPa。但是添加La2O3后低碳镁碳砖自粉化严重,体积密度由3.00 g/cm3降低至2.62 g/cm3,显气孔率由3.57%提高到了8.2%。随着稀土La2O3的加入,低碳镁碳砖的强度下降,抗压强度由34.7 MPa降低至9.6 MPa。添加稀土CeO2、La2O3后低碳镁碳砖的抗渣侵蚀能力均增强,1 600 ℃下在精炼渣中浸泡3 h后,未加稀土的低碳镁碳砖熔损厚度为0.83 mm,添加CeO2后熔损厚度为0.40 mm,添加La2O3后熔损厚度为0.18 mm。

关键词: 低碳镁碳砖, 稀土氧化物, 微观组织, 强度, 抗渣侵蚀能力

Abstract: The differentiated effect of adding rare earth CeO2 and La2O3 on the strength and anti-slag erosion capacity was studied. After the addition of rare earth CeO2, the porosity rate of low carbon magnesia carbon brick was decreased, the volume density and normal temperature compressive strength were increased, and the slag erosion resistance was improved. After the addition of CeO2, low carbon magnesia carbon bricks were more dense, the volume density increased from 3.00 g/cm3 to 3.04 g/cm3, and the porosity rate decreased from 3.57% to 3.16%. With the addition of rare earth CeO2, the strength of low carbon magnesia carbon brick also increased, and the compressive strength increased from 34.7 MPa to 41.3 MPa. However, after the addition of La2O3, low carbon magnesiacarbon brick self-powdered, the volume density decreased from 3.00 g/cm3 to 2.62 g/cm3, and the porosity rate increased from 3.57% to 8.2%. With the addition of rare earth La2O3, the strength of low carbon magnesia carbon brick also decreased, and the compressive strength decreased from 34.7 MPa to 9.6 MPa. The slag erosion resistance of low carbon magnesia carbon bricks was enhanced after adding rare earth CeO2 and La2O3. After 1 600 ℃ for 3 h, the melting loss thickness of low carbon magnesia carbon bricks without the rare earth mixture was 0.83 mm, the  melting loss thickness after adding CeO2 was 0.40 mm, and the  melting loss thickness after adding La2O3 was 0.18 mm.

Key words: low carbon magnesia carbon brick, rare earth oxide, microstructure, strength, anti-slag erosion ability