炼钢 ›› 2023, Vol. 39 ›› Issue (2): 56-61.

• 凝固与浇铸 • 上一篇    下一篇

碲对46MnVS非调质钢中硫化物分布的改质规律

沈  伟, 李志伟, 田钱仁,付建勋   

  1. 上海大学材料科学与工程学院先进凝固技术中心  省部共建高品质特殊钢冶金与制备国家重点实验室,上海 200444
  • 出版日期:2023-04-05 发布日期:2023-04-06

Modification of sulfide distribution in 46MnVS non-quenched and tempered steel by tellurium

  • Online:2023-04-05 Published:2023-04-06

摘要: 以工业生产的含碲46 MnVS非调质钢铸坯中的硫化物为研究对象,结合夹杂物三维腐刻和扫描电镜,观察并分析了铸坯中硫化物等效直径、数量密度和三维形貌的变化规律,总结了碲对硫偏析及硫化物分布的影响规律。研究发现碲改质后的铸坯激冷层到混晶区硫化物等效直径由2.6 μm逐渐增大至5.8 μm,中心等轴晶区硫化物等效直径先减小再增大,椭球型和八面体型硫化物从边部到中心占比由84.2 %逐渐降低至25.7 %。相对于未改质铸坯,碲改质后硫偏析指数减小,最大硫偏析指数由1.13降低到1.06;硫化物的等效直径有所降低,铸坯中椭球型和八面体型硫化物占比增加,激冷层中占比提升最大。

关键词: 46MnVS钢, 碲改质, 硫偏析, 硫化物分布

Abstract: The sulfide in the industrial production of 46MnVS non-quenched and tempered steel slab containing tellurium was taken as the research object, combined with the inclusion three-dimensional etching and scanning electron microscope, the changes of sulfide equivalent diameter, quantitative density and three-dimensional morphology in the slab were observed and analyzed, and the influence of tellurium on sulfur segregation and sulfide distribution was summarized. It was found that the equivalent diameter of sulfide from quench layer to mixed crystal zone of tellurium modified slab  from 2.6 μm gradually increased to 5.8 μm. The effective diameter of sulfides in the central equiaxed zone first decreased and then increased, and the proportion of ellipsoidal and octahedral sulfides from edge to center gradually decreased from 84.2 % to 25.7 %. Compared with the unmodified slab, the sulfur segregation index decreased after tellurium modification,and the maximum sulfur segregation index decreased from 1.13 to 1.06. The equivalent diameter of sulfides decreased, the proportion of ellipsoidal and octahedral sulfides in the slab increased, and the proportion in the quench layer increased the most.

Key words: 46MnVS steel, tellurium modification, sulfur segregation, sulfide distribution