炼钢 ›› 2026, Vol. 42 ›› Issue (5): 104-114.

• 节能环保 • 上一篇    

转炉干法除尘烟道结垢物特性及结垢机理研究

张杰新¹,刘强²,尹川¹,唐萍²,何炳洲²,许彦可²   

  1. 1.重庆钢铁股份有限公司炼钢厂,重庆 401258;2.重庆大学材料科学与工程学院,重庆 400044
  • 出版日期:2026-09-28 发布日期:2026-09-28

Study on the characteristics and formation mechanism of nodule in converter dry de-dusting flue

ZHANG Jiexin¹, LIU Qiang², YIN Chuan¹, TANG Ping², HE Bingzhou², XU Yanke²   

  1. 1.Steelmaking Plant of Chongqing Iron and Steel Company Limited, Chongqing 401258, China;2.College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China
  • Online:2026-09-28 Published:2026-09-28

摘要: 针对转炉干法除尘烟道结垢问题,采用XRF、XRD、SEM等设备对除尘烟道内结垢物特性进行分析,结合热力学计算对烟道结垢机理进行分析。研究表明,转炉干法除尘烟道结垢现象主要集中在烟罩、汽化冷却烟道斜坡、烟道末端、蒸发冷却器内部、香蕉弯区域,产生结垢的原因包括物理结垢和化学结垢。吹炼初期金属喷溅是烟罩结垢的主要原因;烟尘中大量存在的CaO与除尘灰基础氧化物Fe?O?高温反应生成CaFe?O?是汽化冷却烟道斜坡结垢的主要原因;烟尘中ZnO与Fe?O?高温反应形成ZnFe?O?是烟道末端、蒸发冷却器内部结垢的主要原因,同时烟尘中CaO与烟气中CO?作用生成CaCO?会加重蒸发冷却器内部结垢。烟气中含有较高含量的NaCl、KCl低熔点物质会促使烟道结瘤物尺寸增大、强度增加。

关键词: 转炉干法除尘;烟道;结垢物特性;结垢机理

Abstract: In response to the problem of nodule in the converter dry de-dusting flue, the characteristics of nodule were analyzed by XRF, XRD, SEM and other equipment, and the formation mechanism of nodule was analyzed in combination with thermodynamic calculation. The study shows that the nodule phenomenon in the converter dry de-dusting flue is mainly concentrated in the flue hood, the sloping area of the vaporization cooling flue, the end of the vaporization cooling flue, the evaporative cooler interior and banana bend area, and the reasons for the nodule include physical nodule and chemical nodule. Metal splashing in the initial stage of blowing is the main cause of nodule on the flue hood. The presence of a large amount of CaO and the basic oxides Fe?O? in the dust undergoes high-temperature reactions to form CaFe?O?, which is the primary cause of the formation of nodule in the sloping area of the vaporization cooling flue. The high-temperature reaction of ZnO with Fe?O? in the fly ash to form ZnFe?O? is the main reason for nodule at the end of the flue and inside the evaporative cooler, and CaO in the dust reacts with CO? in flue gas to form CaCO?, which will aggravate the nodule inside the evaporative cooler. The flue gas contains a large amount of NaCl and KCl, which are low-melting substances that can cause the size of the nodule in the flue to increase and their strength to augment.

Key words: converter dry de-dusting; flue; characteristics of nodule; formation mechanism of nodule