炼钢 ›› 2026, Vol. 42 ›› Issue (4): 35-42.

• 转炉及电炉冶炼 • 上一篇    下一篇

CaO-SiO2-FeO-Al2O3-MgO渣系发泡性能研究

樊晟宏1,2,王京志2,刘  燊3,赵俊学1,李  欣2,韩培伟2   

  1. 1.西安建筑科技大学 冶金工程学院,陕西 西安 710055;
    2.中国科学院 过程工程研究所,北京 100190;
    3.江西台鑫钢铁有限公司,江西 上饶 334602
  • 出版日期:2026-08-05 发布日期:2026-07-21

Study on the foaming characters of CaO-SiO2-FeO-Al2O3-MgO slag

  • Online:2026-08-05 Published:2026-07-21

摘要: 炉渣的发泡性能对电弧炉埋弧操作与电能效率具有重要影响。针对CaO-SiO2-FeO-Al2O3-MgO五元渣系,首先在均相熔融条件下系统考察其发泡行为。基于热力学计算确定组分范围(w(FeO)=21%~30%、w(MgO)=3%~7%、碱度1.0~2.2),结合单因素试验与物性参数分析得出:FeO质量分数由21%增至25%时,泡沫化指数因黏度下降而显著提高;继续增至30%时,因密度与表面张力上升,增幅趋缓;碱度提高使泡沫化指数呈非单调变化,在1.25处出现极小值,1.7处出现极大值,此为黏度降低与表面张力、密度增大共同作用的结果;MgO含量对泡沫化指数影响较小,因其对黏度与表面张力的调节能力有限。此外,通过开展高温固液两相试验(液相成分相近),发现固体颗粒含量对发泡行为的影响呈抛物线型变化。

关键词: 电弧炉, CaO-SiO2-FeO-Al2O3-MgO渣, 发泡性能, 均相熔融, 固体颗粒

Abstract: The foaming behavior of slag significantly influences the submerged arc operation and energy efficiency of electric arc furnaces. The foaming characteristics of the CaO-SiO2-FeO-Al2O3-MgO slag system under homogeneous melting conditions were systematically investigated. Based on thermodynamic calculations, the experimental composition ranges were determined as follows: w(FeO)=21%-30%,w(MgO)=3%-7%, and basicity 1.0-2.2. Through single-factor experiments and physical property analysis, the following conclusions were drawn: as the mass fraction of FeO increased from 21% to 25%, the foaming index rose significantly due to decreased viscosity. And a further increase to 30% slowed the growth trend, attributed to increased density and surface tension. Increasing basicity caused a non-monotonic change in the foaming index, with a minimum observed at 1.25 and a maximum at 1.7, resulting from the combined effects of decreased viscosity and increased surface tension and density. The mass fraction of MgO showed a negligible effect on the foaming index, owing to its limited ability to modify viscosity and surface tension. Additionally, high-temperature experiments involving solid-liquid mixtures (with similar liquid phase composition) revealed that the solid particle content affected foaming behavior in a parabolic trend.

Key words: electric arc furnace, CaO-SiO2-FeO-Al2O3-MgO slag, foaming behavior, homogeneous melting, solid particles