炼钢 ›› 2024, Vol. 40 ›› Issue (2): 1-22.

• 专题论述 •    下一篇

超低碳IF钢冶炼过程炉渣对夹杂物控制研究进展

王  亮,杨  健,张同生,张银辉   

  1. 上海大学材料科学与工程学院 省部共建高品质特殊钢冶金与制备国家重点实验室,上海 200444
  • 出版日期:2024-04-05 发布日期:2024-04-02

State of the art in the control of inclusions by slag in steelmaking process of ultra-low carbon IF steel

  • Online:2024-04-05 Published:2024-04-02

摘要: 超低碳IF钢板主要应用于汽车面板等超深冲部件,其面临的主要质量问题是夹杂物、卷渣、气泡造成的炼钢缺陷,因此全生产流程中所采用的炉渣性质对控制炼钢缺陷具有重要作用。分别从炉渣的物化特性以及所在工序炉渣特性两个角度归纳总结了炉渣对夹杂物控制产生的影响,发现炉渣对夹杂物的吸附溶解与炉渣的物化性质和夹杂物的尺寸相关。RH精炼渣主要控制目标是低氧化性和合适的w(CaO)/w(Al2O3),TFe质量分数一般控制在2.0 %~8.0 %,w(CaO)/w(Al2O3)控制在1.2~1.8,此外精炼渣碱度一般控制较高为4.0~10.0。中间包覆盖剂和结晶器保护渣首先要防止钢液增碳,其次是防止渣中SiO2造成钢液的二次氧化,同时它们还应拥有良好的吸附夹杂物的能力。超低碳IF钢中间包高碱度覆盖剂一般碱度为2.9~11.5,w(CaO)/w(Al2O3)控制在1.0~2.5,(FeO +MnO)质量分数控制在1.9 %~4.0 %。而超低碳IF钢结晶器保护渣的碱度一般控制较低在0.85~1.0,w(CaO)/w(Al2O3)控制在5.0~8.5,(FeO+MnO)质量分数小于1 %。

关键词: 超低碳IF钢, Al2O3夹杂物, 精炼渣, 中间包覆盖剂, 结晶器保护渣, 二次氧化

Abstract: Ultra-low carbon IF steel sheet is mainly used in ultra-deep drawing parts such as automotive exposed panel, etc., which is faced with main surface quality problems caused by the steelmaking defects of inclusions, mold flux entrapment and bubbles. Therefore, the slag properties used in the whole steelmaking process play an important role in controlling inclusions in steel. In the present paper, the effects of slag on inclusion control were summarized from two aspects of the slag physicochemical properties and the slag characteristics in different steelmaking stages. It was found that the adsorption and dissolution of inclusions by slag was related to the physicochemical properties of slag and the sizes of inclusions. The main control objectives of RH refining slag were low oxidation and appropriate w(CaO)/w(Al2O3). The TFe mass fraction was generally controlled in 2.0 %–8.0 %, and the w(CaO)/w(Al2O3) was controlled in 1.2–1.8. In addition, the basicity of refining slag was generally controlled in 4–10. The tundish flux and mold flux should first prevent the carbon increase in the molten steel, and secondly prevent the secondary oxidation of the molten steel caused by SiO2 in the slag. At the same time, they should also be capable of adsorbing inclusions. The high basicity tundish flux for ultra-low carbon IF steel generally had the basicity of 2.9–11.5, the w(CaO)/w(Al2O3) was controlled in 1.0–2.5, and the (FeO +MnO) mass fraction was controlled in 1.9 %–4.0%. The basicity of the mold flux for ultralow carbon IF steel was generally controlled in 0.85–1.0, the w(CaO)/w(Al2O3)  was controlled in 5.0–8.5, and the (FeO+MnO) mass fraction was less than 1 %.

Key words: ultra-low carbon IF steel, Al2O3 inclusions, refining slag, tundish flux, mold flux, secondary oxidation