炼钢 ›› 2023, Vol. 39 ›› Issue (6): 53-58.

• 炉外精炼 • 上一篇    下一篇

37Mn5钢精炼过程大尺寸Al2O3-SiO2-MnO类夹杂物形成与演变机理

苗志奇1,成国光1,李世健1,任振海2,徐必靖2   

  1. 1.北京科技大学 钢铁冶金新技术国家重点实验室,北京 100083;
    2.中天钢铁集团 电炉厂,江苏 常州 213011
  • 出版日期:2023-12-05 发布日期:2023-12-06

Formation and evolution mechanism of large-size Al2O3-SiO2-MnO inclusions in 37Mn5 steel refining process

  • Online:2023-12-05 Published:2023-12-06

摘要: 为探究37Mn5钢精炼过程尺寸在10 μm以上的大尺寸Al2O3-SiO2-MnO类夹杂物的形成与演变机理,在实际“EAF→LF→VD→钙处理→CC”工艺生产37Mn5钢的精炼全流程进行系统取样,检测了钢液成分并重点分析了不同冶炼阶段大尺寸Al2O3-SiO2-MnO类夹杂物的形貌和成分特征,结合实际生产工艺与热力学计算,揭示了这类夹杂物的演变规律。研究结果表明:由于出钢过程局部钢液Al含量低而O含量高,大尺寸Al2O3-SiO2-MnO夹杂物形成;LF精炼初期,局部Ca含量增加形成Al2O3-SiO2-MnO-CaO夹杂物;LF精炼中期以后Ti含量增加会变性前期形成的这两类夹杂物,形成含TiOx的夹杂物,随着冶炼的进行,Ti元素在夹杂物中分布逐渐均匀;VD后钙处理量不足导致夹杂物变性效果不理想,对大尺寸夹杂物的影响不大。出钢过程合理的脱氧、合金化和造渣制度可以减少Al2O3-SiO2-MnO类夹杂物的形成,从而减少夹杂物数量,改善钢材质量。

关键词: 37Mn5 钢, 钢液精炼, 夹杂物, 洁净度

Abstract: In order to explore the formation and evolution mechanism of large-size Al2O3-SiO2-MnO inclusions with the size of more than 10 〖WTBZ〗μ〖WTB4〗m in 37Mn5 steel refining process, the molten steel was systematically sampled during the whole refining process of EAF-LF-VD-calcium treatment-continuous casting for production of 37Mn5 steel. The composition of molte steel was detected, and the morphology and composition characteristics of large-size Al2O3-SiO2-MnO inclusions in different smelting stages were analyzed. Based on actual production process and thermodynamic calculation, the evolution law of this kind of inclusion was revealed. The results show that, due to the low Al content and high O content in local molten steel during EAF tapping process, large-size Al2O3-SiO2-MnO inclusions are formed. At the beginning of LF refining, the local Ca content increases to form Al2O3-SiO2-MnO-CaO inclusions. After the middle stage of LF refining, the Ti content increases to modify the two kinds of inclusions formed at the early stage to form inclusions containing TiOx. With the progress of smelting, the distribution of Ti is gradually uniform in the inclusions. Insufficient calcium treatment after VD results in unsatisfactory modification of inclusions, and has little effect on the large-size inclusions. Reasonable deoxidation, alloying and slagging process can reduce the formation of Al2O3-SiO2-MnO-CaO inclusions, so as to reduce the number of inclusions and improve the quality of steel.

Key words: 37Mn5 steel, steel refining, inclusion, cleanliness