炼钢 ›› 2023, Vol. 39 ›› Issue (4): 88-92.

• 节能环保 • 上一篇    

转炉气化脱磷渣用于铁水脱磷及节能减排评估研究

佟  帅,李晨晓,王书桓,艾立群,薛月凯,孙华康   

  1. 华北理工大学 冶金与能源学院,河北 唐山 063210
  • 出版日期:2023-08-05 发布日期:2023-07-25

Evaluation of dephosphorization and energy saving and emission reduction of molten iron by converter gasification dephosphorization slag

  • Online:2023-08-05 Published:2023-07-25

摘要: 目前在溅渣护炉过程中进行气化脱磷是一种有效的炉渣除磷技术。为保证转炉熔渣气化脱磷后循环利用的冶炼效果,在实验室进行了气化脱磷渣作为返料用于造渣脱磷的试验研究。研究结果表明,气化脱磷渣用于铁水脱磷时前期脱磷能力强,终点脱磷率低,其终点铁水脱磷率和脱磷速率分别为53.3  %和0.16 %/min;对比配制脱磷剂炉次可知,配制脱磷剂前期脱磷效果差,终点脱磷率高,其终点铁水脱磷率和脱磷速率分别为91.6 %和0.32 %/min。根据两者脱磷剂的脱磷优势采用混合配比铁水脱磷,当气化脱磷渣大比例用于铁水脱磷时出现回磷现象;当混合比例为1∶4时脱磷效果最好,终点脱磷率为64.4 %。采用生命周期评价法对混合渣料比例为1∶4铁水脱磷进行CO2减排评估,从系统边界的起点到终点预估吨钢可减排CO2  6.034~10.34 kg,吨钢可节省石灰成本1.8~3.0元。

关键词: 气化脱磷渣, 循环利用, 脱磷率, 生命周期评价, 减排

Abstract: At present, the gasification dephosphorization in the process of slag splash protection is an effective slag dephosphorization technology. In order to ensure the effect of smelting and recycling after converter slag gasification dephosphorization, an experimental study on the use of gasification dephosphorization slag as a return material for slagging and dephosphorization was carried out in the laboratory. The research results show that the gasification dephosphorization slag is used for the dephosphorization of molten iron with strong dephosphorization ability in the early stage and low dephosphorization rate at the end point. The dephosphorization ratio and dephosphorization rate of hot metal at the end point are 53.3 % and 0.16 %/min respectively. Comparing the preparation of dephosphorization agent, it can be seen that the dephosphorization effect of the dephosphorization agent is poor in the early stage, and the dephosphorization rate at the end point is high, the final hot metal dephosphorization ratio and dephosphorization rate are 91.6 % and 0.32 %/min, respectively. According to the dephosphorization advantages of the two dephosphorization agents, the mixed ratio of molten iron is used for dephosphorization. When a large proportion of gasification dephosphorization slag is used for dephosphorization of molten iron, the phenomenon of phosphorus reversion occurs; when the mixing ratio is 1∶4, the dephosphorization effect is the best, and the end point dephosphorization ratio is 64.4 %. The CO2 emission reduction assessment was carried out for molten iron dephosphorization with a ratio of 1∶4 mixed slag  using the life cycle assessment method, and the CO2 emission reduction per ton of steel was estimated from the beginning to the end of the system boundary by 6.034-10.34 kg, and the ton of steel could save 1.8-3.0 yuan of lime.

Key words: gasification dephosphorization slag, recycling, dephosphorization rate, life cycle assessment, emission reduction