炼钢 ›› 2023, Vol. 39 ›› Issue (4): 1-12.

• 专题论述 •    下一篇

钢中硫化锰夹杂控制的机理分析与工业实践

刘洪波1,康  举2,谢荣圆3,康  旭1   

  1. 1.河钢材料技术研究院,河北 石家庄 050023;
    2.北京石油化工学院 深水油气管线关键技术与装备北京市重点实验室,北京 102617;
    3.河钢数字技术股份有限公司,河北 石家庄 050000
  • 出版日期:2023-08-05 发布日期:2023-07-25

Mechanism analysis and industrial practice of manganese sulfide inclusion control in steel

  • Online:2023-08-05 Published:2023-07-25

摘要: 钢中MnS夹杂的控制是一个涉及到包括冶炼、凝固、加热和轧制过程等多工序,需要多变量协同控制的系统工程。详细论述了国内外MnS夹杂的研究现状,阐述了不同元素、热处理和轧制工艺对MnS夹杂的影响机理;整理总结了当前MnS夹杂的工艺控制措施,通过采用合适的脱氧工艺提高凝固前沿氧含量、降低精炼渣碱度、采用合适的钙处理工艺、采用低碱度中间包覆盖剂、提高二冷水量加强冷却、降低电磁搅拌强度等方式能够有效地控制MnS夹杂形貌、尺寸和数量。近年来,针对MnS夹杂的变性处理和弥散化分布等控制难点,提出了一些新思路,即向钢液中添加Mg、Ca-Mg、Zr、Ce、Te等元素能够有效控制钢中MnS夹杂形貌、尺寸和数量。

关键词: MnS夹杂, 微观组织, 机械性能, 夹杂物改性, 热处理, 工业实践

Abstract: The control of MnS inclusions in steel is a system engineering which involves multiple processes including smelting, solidification, heating and rolling, and requires multi-variable cooperative control. In this paper, the research status of MnS inclusions at home and abroad was discussed in detail, and the influence mechanism of different elements, heat treatment and rolling process on MnS inclusions were expounded. In addition, the current process control measures of MnS inclusions were summarized. The morphology, size and quantity of MnS inclusions can be effectively controlled by adopting appropriate deoxygenation process, improving the oxygen content at the solidification front, reducing the basicity of refining slag, adopting appropriate Ca treatment process, adopting low basicity tundish covering agent, increasing the secondary cooling water volume, strengthening cooling and reducing electromagnetic stirring intensity. In recent years, some new ideas have been proposed to control the deformation treatment and diffusion distribution of MnS inclusions. The morphology, size and quantity of MnS inclusions in steel can be effectively controlled by adding Mg, Ca-Mg, Zr, Ce and Te elements into molten steel.

Key words: MnS inclusions, microstructure, mechanical property, inclusion modification, heat treatment, industrial practice