炼钢 ›› 2026, Vol. 42 ›› Issue (4): 105-114.

• 产品工艺与质量控制 • 上一篇    

高氧搪瓷钢冶炼工艺研究与实践

李广帮1,2,赵  亮1,2,孙  深1,2,魏崇一1,2   

  1. 1.海洋装备金属材料及其应用全国重点实验室,辽宁 鞍山 114009;
    2.鞍钢集团钢铁研究院 炼钢技术研究所,辽宁 鞍山 114009
  • 出版日期:2026-08-05 发布日期:2026-07-21

Research and practice on smelting process of high oxygen enamel steel

  • Online:2026-08-05 Published:2026-07-21

摘要: 通过碳氧反应热力学计算和钢液中产生CO的理论分析,高氧搪瓷钢液本身在凝固时不会产生气泡,在连铸时需要控制中包覆盖剂、连铸保护渣中的碳含量。采取中试试验和连铸生产的方式,得出随着高氧搪瓷钢中活度氧值的增加,钢中全氧含量相应地增加,钢中夹杂物数量增多,最大夹杂物尺寸呈增大趋势,当活度氧值达到0.028 5%时,最大夹杂物尺寸超过30 μm。钢锭中合金收得率随着钢液中活度氧值的增加而降低,当活度氧值由0.011 6%增加到0.028 5%,钢锭中锰的收得率由93%下降到84.2%,铌的收得率由76.2%下降到68%。高氧搪瓷钢连铸坯中夹杂物呈球形,主要由氧化物和硫化锰组成,氧化物中以氧化锰为主,硫化锰分布在氧化物的表面,上述夹杂物均为塑性夹杂,在轧制过程中与钢板同步变形。质量良好的连铸坯,经热轧、冷轧和涂搪后,产品使用效果良好。

关键词: 高氧搪瓷钢, 碳氧积, 合金收得率, 夹杂物

Abstract: Through thermodynamic calculations of carbon-oxygen reactions and theoretical analysis of CO production in molten steel, it is concluded that bubbles are not generated by the high oxygen enamel steel itself  during solidification. Therefore,during the continuous casting of high oxygen enamel steel, it is necessary to control the carbon content in the tundish flux and continuous casting mould power. By adopting pilot experiments and continuous casting production methods, it was found that as the active oxygen value in the high oxygen enamel steel increased, the total oxygen content also increased, the number of inclusions increased, and the maximum size of inclusions showed an increasing trend. When the active oxygen value reached 0.028 5%, the maximum size of inclusions exceeded 30 μm. The yield of alloy in the steel ingot decreased with the increased of active oxygen value in the molten steel. When the active oxygen value increased from 0.011 6% to 0.028 5%, the yield of Mn in the steel ingot decreased from 93% to 84.2%, and the yield of Nb in the steel ingot decreased from 76.2% to 68%.The inclusions in the high oxygen enamel steel continuous casting slab were spherical and mainly composed of oxides and manganese sulfide. Manganese oxide was the main component in the oxides, while manganese sulfide was distributed on the surface of the oxides. The above-mentioned inclusions were plastic inclusions that deform synchronously with the steel plate during the rolling process. After hot rolling, cold rolling, and enamel, high-quality continuous casting slab have good product performance.

Key words: high oxygen enamel steel, carbon-oxygen equilibrium, alloy yield, inclusion