炼钢 ›› 2026, Vol. 42 ›› Issue (2): 65-75.

• 产品工艺与质量控制 • 上一篇    下一篇

“VD→LF→钙处理→连铸连轧”工艺生产低碳铝镇静钢过程洁净度和夹杂物演变

马文俊1,杨  文2,郝丽霞3,喻东前2,张立峰4   

  1. 1.首钢股份公司迁安钢铁公司 迁顺技术中心,河北 唐山 064400;
    2.北京科技大学 冶金与生态工程学院,北京 100083;
    3.首钢股份公司迁安钢铁公司 炼钢部,河北 唐山 064400;
    4.北方工业大学 机械与材料工程学院,北京 100144
  • 出版日期:2026-04-05 发布日期:2026-03-27

Evolution of cleanliness and inclusions of a low-carbon aluminum killed steel producted by the route of “VD-LF-Ca treatment-continuous casting and rolling”

  • Online:2026-04-05 Published:2026-03-27

摘要: 研究了转炉工艺下“VD→LF→钙处理→连铸连轧”流程生产低碳铝镇静钢过程钢液洁净度和钢中夹杂物演变特征。研究发现,LF精炼过程钢中T.O质量分数由进站时的129×10-6显著降至钙处理前的34×10-6,但依旧存在精炼渣中w(CaO)/w(Al2O3)偏小的问题。钙处理后钢中T.O和T.N含量都增加明显,发生明显的二次氧化,需加强钙处理过程的稳定化控制。脱氧后的精炼过程,夹杂物由簇群状Al2O3转变为不规则Al2O3-MgO,在以0.64 kg/t的钙线喂入量进行钙处理后转变为球形CaO·2Al2O3。由于钙处理过程大量小尺寸夹杂物的生成,通过自动扫描电镜检测得到夹杂物平均尺寸由钙处理前的2.8 μm降至钙处理后的2.3 μm,但同时由于钙处理过程精炼渣卷入等因素导致钙处理后夹杂物最大尺寸增至28 μm。由于浇铸过程钢液发生二次氧化,自动扫描电镜检测结果显示中间包钢液中夹杂物数密度显著增加至45个/mm2,夹杂物面积分数也高达268×10-6,因此还需进一步加强连铸过程钢液的保护浇铸。

关键词: 低碳铝镇静钢, 洁净度, 夹杂物, 钙处理, 二次氧化

Abstract: The evolution characteristics of the steel cleanliness and inclusions in a low-carbon aluminum killed steel produced by the the route of VD→ LF→calcium treatment→continuous casting and rolling under the converter process was investigated. It was found that the T.O mass fraction significantly decreased from 129×10-6 at the LF start to 34×10-6 before calcium treatment. But, there was still a problem that the w(CaO)/w(Al2O3) in the refining slag was too small. A significant increase on the contents of T.O and T.N in the steel after calcium treatment, indicating that the significant reoxidation occurred. It was necessary to strengthen the stabilization control of the calcium treatment process. During the refining process after deoxidation, the inclusions transformed from clustered Al2O3 to irregular Al2O3-MgO, and then to spherical CaO·2Al2O3 after the calcium treatment with a feeding amount of 0.64 kg/t steel. Due to the generation of a large number of small-sized inclusions during the calcium treatment process, the average size of inclusions decreased from 2.8 μm before calcium treatment to 2.3 μm after calcium treatment according to the detection of automatic SEM. However, at the same time, factors such as the entrainment of refining slag particles during calcium treatment increased the maximum size of inclusions to 28 μm after calcium treatment. Due to the reoxidation of the molten steel during the casting process, the number density of inclusions in the molten steel in tundish significantly increased to 45/mm2, and the area fraction of inclusions also reached 268×10-6 based on the detection results of automatic SEM. Therefore, it was necessary to further strengthen the protective casting of the molten steel during the continuous casting process.

Key words: low-carbon aluminum killed steel, cleanliness, inclusion, calcium treatment, reoxidation