炼钢 ›› 2025, Vol. 41 ›› Issue (6): 97-106.

• 产品工艺与质量控制 • 上一篇    下一篇

氧和硫含量对低碳钢炼钢连铸过程夹杂物演变的影响

邹偲文1,杨  健1,张银辉1,赵加全2,徐  阳2,王朋飞2,王彦兵2   

  1. 1.上海大学材料科学与工程学院 省部共建高品质特殊钢冶金与制备国家重点实验室,上海 200444;
    2.河北天柱钢铁集团有限公司,河北 唐山 063610
  • 出版日期:2025-12-05 发布日期:2025-11-28

Influence of oxygen and sulfur content on the evolution of inclusions in steelmaking and continuous casting process for low-carbon steel

  • Online:2025-12-05 Published:2025-11-28

摘要: 对比分析了不同氧、硫含量Q195L钢的两炉次钢(G85和G86)在转炉终点、氩站进站、氩站出站、中间包和连铸坯中的夹杂物形貌、数量、尺寸及成分变化,结合热力学计算和钢样、渣样成分分析,探讨了夹杂物的演变规律。结果表明,Q195L钢中主要存在Al2O3夹杂、MnS夹杂及Al2O3+MnS复合夹杂,这与热力学计算结果一致。从转炉终点到氩站进站5μm以上Al2O3夹杂数量密度大幅增加,这是因为在转炉出钢过程中加高纯铝锭进行脱氧所致。钢中的氧含量主要影响大型夹杂物的含量,G85炉次中间包钢液O元素含量高于G86炉次,导致其5 μm以上Al2O3夹杂含量明显高于G86炉次。钢中的S元素含量主要影响细小MnS夹杂物的含量,G85炉次氩站进站后钢液S元素含量低于G86炉次,导致其0.2 μm以上MnS含量低于G86炉次。该研究结果为低成本洁净钢平台技术的优化提供了理论依据。

关键词: 低碳钢, 夹杂物演变, 氧含量, 硫含量

Abstract: The morphologies, quantities, sizes, and composition changes of inclusions in two heats of Q195L steel with different oxygen and sulfur contents (G85 and G86) were compared and analyzed for the samples of the converter end, the inlet and outlet of the argon station, the tundish, and the continuous casting slab. Combined with thermodynamic calculations and analysis of the compositions of steel and slag samples, the evolution law of inclusions was studied. The results indicate that the Q195L steel mainly contains Al2O3 inclusions, MnS inclusions, and Al2O3+MnS composite inclusions, which is consistent with the thermodynamic calculation results. The number density of Al2O3 inclusions with a diameter greater than 5 μm increases significantly from the converter end to the inlet of the argon station. This is because high-purity aluminum blocks are added for deoxidation during the converter tapping process. The oxygen content in steel mainly affects the content of large-size inclusions. The O element content in the tundish of G85 heat is higher than that of G86 heat, resulting in a significantly higher content of Al2O3 inclusions greater than 5 μm compared to G86 heat. The sulfur content in steel mainly affects the content of fine MnS inclusions. After the inlet of the argon station, the S element content in the molten steel of G85 heat is lower than that of G86 heat, resulting in the content of MnS inclusions greater than 0.2 μm lower than that of G86 heat. The research results provide a theoretical basis for the optimization of the low-cost clean steel platform technology.

Key words: low carbon steel, inclusion evolution, oxygen content, sulfur content