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含硼低碳钢板坯鼓包缺陷的原因分析及控制

左康林,邓丽琴,江中块   

  1. (上海梅山钢铁股份有限公司,江苏 南京 210039)
  • 接受日期:1900-01-01 出版日期:2018-04-05

The origin and control of blister defects on slabs of boron-bearing low-carbon steel

  • Accepted:1900-01-01 Online:2018-04-05

摘要: 针对梅钢含硼低碳钢板坯出现鼓包缺陷的问题,采用气相色谱仪、Heraeus测氢仪、扫描电镜(SEM)和电化学方法研究了鼓包缺陷产生原因及影响因素,利用Gleeble-3500热模拟试验机对比了未经镁处理及经镁处理板坯的高温塑性。结果表明:鼓包缺陷处存在大尺寸的Al2O3夹杂;鼓包缺陷内CH4和H2质量分数分别为45.86 %和51.79 %;板坯中心硼元素的正偏析是导致鼓包缺陷发生的重要原因。采用钢水镁处理工艺改善了板坯质量,中心偏析降低至1.8,大于50μm的夹杂物数量比例降低到0.63 %。优化了梅钢转炉冷却料与钢包渣改质剂的加入制度,晴天时冷却料全部为矿石,雨天时优先加入球团矿,但不多于31 kg/t,不足由矿石替代;钢包渣改质剂加入量小于1.5 kg/t,不足由生石灰代替。工艺优化后,梅钢板坯鼓包缺陷月平均发生率由5次/月降低至0.78次/月。

关键词: 鼓包缺陷, 含硼低碳钢, 氢, 镁处理

Abstract: In order to control the blister defects on the slab of boron-bearing low-carbon steels in Meishan steel, gas chromatograph, Heraeus hydrogen gauge, SEM and method of electrochemistry were used to analyze the cause and effect factors of blister defects on the slab. High temperature plasticity of slabs with and without Mg treatment were tested with Gleeble-3500 thermal simulation test machine. Then improvement measures were proposed in accordance with Meishan Steel. The results showed that big Al2O3 inclusions were found in the blisters, the mass fraction of CH4 and H2 were 45.86 % and 51.79 % respectively inside the blisters, and positive segregation of B in the center of slab was the important effect factors of blister defects. Mg treatment was used to improve the quality of the slab, resulting in that the center segregation reduced to 1.8 and the number of inclusions larger than 50 μm reduced to 0.63%. Coolant addition in converter and addition of ladle slag modifier were also optimized. In sunny days, the coolant addition was all iron ore; and in rainy days, less than 31 kg/t pellets and complemental iron ore were added to converter as coolant. The addition of ladle slag modifier was less than 1.5 kg/t and complemented by lime. After process optimization, the frequency of blister defects in month average reduced from 5 to 0.78 in Meishan Steel.

Key words: blister defect, boron-bearing low-carbon steel, hydrogen, Mg treatment