炼钢 ›› 2019, Vol. 35 ›› Issue (6): 12-15.

• 转炉及电炉冶炼 • 上一篇    下一篇

近平衡条件下高氮钢中氮元素行为研究

鲍振东1,屈天鹏2,施利魏2,王德永2   

  1. (1.本溪钢铁(集团)有限责任公司,辽宁 本溪117021; 2.苏州大学 沙钢钢铁学院,江苏 苏州 215021)
  • 接受日期:1900-01-01 出版日期:2019-12-05

Nitrogen behavior in high nitrogen steel during near equilibrium condition

  • Accepted:1900-01-01 Online:2019-12-05

摘要: 高氮钢凝固过程普遍存在氮元素逃逸现象,基于近平衡模拟试验和热力学分析,研究了焊丝钢中氮元素含量、体系氮分压以及冷却速度对于熔池中氮含量的影响规律。当焊丝钢中氮质量分数从0.15 %增加到0.90 %,熔池中氮含量达到原来的2倍以上。通过增加体系氮分压或增加整体压力均有利于提高熔池氮含量。通过提高冷却速率可以提高熔池氮质量分数30 %以上。研究结果对于抑制高氮钢中氮逃逸行为具有重要的指导意义。

关键词: 高氮钢, 凝固行为, 氮逃逸, 强制冷却

Abstract: Nitrogen loss was primal problem during solidification process of HNS (High Nitrogen Steel). Based on thermodynamic analysis and near equilibrium experiment, the effects of wire steel composition and cooling rate on nitrogen content in melt pool were researched. Under the present conditions, it came to the following conclusions. When the nitrogen mass fraction in wire steel increase from 0.15 % to 0.90 %, the nitrogen content in pool was increased by more than two times. It will be useful to increase ratio of nitrogen in shielding gas. More and more nitrogen were kept in pool as solid-solution state rather than nitrogen bubble with increasing of cooling rate. The nitrogen content increased by more than 30 % under forced cooling design developed in the present study. The results of this paper will provide theoretical guide for controlling the escape of nitrogen element in HNS.

Key words: high nitrogen steel;solidification behavior, nitrogen loss;forced cooling