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IF钢生产过程中Al-Ti-Mg-O类夹杂物的演变行为

肖鹏程1,2,张仕骏1,2,刘增勋1,2,朱立光1,2   

  1. 1.华北理工大学 冶金与能源学院,河北 唐山 063009 2.河北省高品质钢连铸工程技术研究中心,河北 唐山 063009

  • 接受日期:1900-01-01 出版日期:2018-02-05

Evolution of Al-Ti-Mg-O inclusions during refining and casting process of interstitial free steel

  • Accepted:1900-01-01 Online:2018-02-05

摘要: 采用扫描电镜和热力学分析,对IF钢生产过程中Al-Ti-Mg-O类夹杂物的成分、尺寸和形貌的特征及演变行为进行了研究。结果表明,RH脱氧后夹杂物主要为纯Al2O3,合金化以后到浇铸成连铸坯的过程中夹杂物中Al2O3占比不断减小,含Ti类和含Mg类夹杂物占比不断增加;纯Al2O3夹杂尺寸较大,含Ti夹杂物尺寸较小。在热力学平衡条件下,钢中的夹杂物应为Al2O3稳定存在,但二次氧化和局部Ti浓度的升高促进了TiOx的生成。夹杂物中TiOx含量的增加,将会降低Al-Ti-Mg-O类夹杂物熔点。

关键词: IF钢, 夹杂物演变, Al-Ti-Mg-O类夹杂物, 夹杂物热力学

Abstract: The evolution of chemical composition,size,proportion,and morphology of the Al-Ti-Mg-O inclusions during the steelmaking process of interstitial free (IF) steel were investigated by means of Auto-SEM. Results showed that after RH deoxidation,the main inclusions were pure Al2O3 inclusions. Then the proportion of Al2O3 in inclusions decreased,while the proportion of inclusions containing titanium and magnesium increased from RH deoxidation to slab. The size of pure Al2O3 inclusions was larger and the size of inclusions containing titanium was smaller. Thermodynamic analysis resulted showed that the inclusions should be stable with Al2O3 at the concentration of molten steel. But the titanium alloying and spontaneous enrichment would make a high titanium concentration environment that was in favor of the TiOx existence. Moreover,more TiOx component could control Al-Ti-Mg-O inclusions with a lower melting temperature.

Key words: interstitial free steel, inclusion evolution, Al-Ti-Mg-O inclusions, inclusion thermodynamics