炼钢 ›› 2016, Vol. 32 ›› Issue (6): 45-50.

• 炉外精炼 • 上一篇    下一篇

精炼工艺对SPA-H钢卷洁净度的影响

  

  1. 1.首钢技术研究院,北京 100043;
    2.首钢京唐钢铁联合有限责任公司 炼钢部;河北 唐山 063200
  • 接受日期:1900-01-01 出版日期:2016-12-05

Effect of refining procedures on inclusion characteristics in SPA-H steel coils

  • Accepted:1900-01-01 Online:2016-12-05

摘要: 某钢厂为节约炼钢成本,试图采用CAS工艺替代传统LF工艺精炼SPA-H钢,但是否会影响钢材洁净度仍存争议。采用总氧分析与ASPEX扫描电镜的自动特征分析功能研究了SPA-H钢卷的洁净度,并对比了CAS与LF工艺的夹杂物特征。结果表明:两种精炼工艺生产的钢卷w(T.O)=(18~19)×10-6,相差不大。钢卷中显微夹杂物主要有CaS-Al2O3,Al2O3,(Ca,Mn)S和TiN夹杂物,大型夹杂物全部为纯MnS夹杂物。典型CAS工艺炉次轧板的显微夹杂物主要是(Ca,Mn)S和Al2O3, 而典型LF精炼工艺炉次轧板的显微夹杂主要为CaS-Al2O3夹杂物(比例达81.3 %)。CAS工艺的大型MnS夹杂物数量明显高于LF工艺,与Factsage热力学计算吻合较好。夹杂物特征差异的原因是试验CAS工艺炉次的精炼渣平均w(TFe)=2.1 %高于LF工艺(0.6 %),CAS工艺在硫含量和喂钙吸收率控制上不如LF工艺,导致钢中w(Ca)/w(S)小于LF工艺,因此,为减少大型夹杂物数量,采用低成本CAS工艺精炼SPA-H应加强钙处理效果和顶渣改质。

关键词: SPA-H钢, 夹杂物, LF精炼, CAS精炼, 洁净度

Abstract: To reduce the cost, one steel mill try to use CAS refining to replace traditional LF refining process in SPA-H steel. However, it is still in dispute whether this replacement may worsen the cleanliness of steel coils. The total oxygen content and automatic feature analysis (AFA) in ASPEX SEM were used to evaluate the cleanliness of SPA-H steels coils, and the effect of refining methods,such as CAS refining and LF refining process on them were compared. The result shows that the T.O mass fraction of coils were almost the same, ranging from 18×10-6 to 19×10-6, Four different kinds of micro inclusions were detected in steel coils: CaS-Al2O3,Al2O3,(Ca,Mn)S and TiN, and all the macro inclusions were pure MnS. Furthermore, (Ca,Mn)S and Al2O3 inclusions account for over 90 % of inclusions in CAS refining process while CaS-Al2O3dominates micro inclusions in steels coils for LF refining process, occupying 81.3 %.The number density of largesized inclusions for CAS refining process were much larger than that for LF refining process. Equilibrium inclusion composition calculated by Factsage agree well with the experimental results. Lower calcium yield ratio and smaller Ca/S ratio for CAS refining process due to the relatively higher TFe content in refining slag may account for the difference of the inclusions between the two different refining methods. Accordingly, Ca alloy should be more added and top slag should be reduced when refining SPA-H steels using CAS process.