关键词: 异相形核(Ti, Nb, V)(C, N)析出相, H13热作模具钢, Nb, 生成机理, Thermo-Calc

Abstract: The precipitation of carbonitride in H13 hot working die steel would be detrimental to the strength, hardness, toughness and fatigue resistance properties of steel. The characteristics of heterogeneous precipitates (Ti,Nb,V)(C,N) with the size larger than 1 μm in a Nb containing H13 forging bar pre-produced by electro-slag remelting (ESR) process were studied. The generation mechanism was analyzed through calculation by Thermo-Calc software. Most of the precipitates observed consisted of three-layer structures. The center was an oxide core which was mainly MgO-Al2O3 spinel or Al2O3, the middle layer was a Ti-V-rich (Ti,Nb,V)(C,N) phase and the outer layer was a Nb-rich (Ti,Nb,V)(C,N) layer. The normalized compositional distributions of Ti, Nb and V in the Ti-V-rich and Nb-rich layers were concentrated. The average composition of Ti-V-rich layer was (Ti0.477V0.337Nb0.187)CxNy and that of Nb-rich layer was (Ti0.127V0.255Nb0.617)CxNy. The size of the heterogeneous precipitates could be up to ten microns. The generation mechanism of the precipitates could be well speculated through Thermo-Calc calculation. The spinel and alumina have already existed in the liquid steel before solidification. During solidification the Ti-rich phase will firstly start to precipitate on the oxide when the solid fraction reaches 0.823. Then the V-rich phase and Nb-rich phase will precipitate successively. During the subsequent heat treatment process, the V-rich phase will be dissolved in Ti-rich phase, resulting in the appearance of large precipitate with three-layer structure.

Key words: heterogeneous (Ti,Nb,V)(C,N), H13 hot working die steel, Nb, generation mechanism, Thermo-Calc