›› 2016, Vol. 32 ›› Issue (3): 50-54.

• 产品工艺与质量控制(含特钢) • 上一篇    下一篇

钙脱氧和镁脱氧的氧化物冶金工艺效果对比

王睿之1,杨健2,祝凯2,王毓男2   

  1. 1. 宝钢研究院炼钢所
    2. 宝山钢铁股份有限公司 中央研究院
  • 收稿日期:2016-01-22 修回日期:2016-02-24 接受日期:1900-01-01 出版日期:2016-06-05 发布日期:2016-06-15
  • 通讯作者: 王睿之 E-mail:wangruizhi@baosteel.com

Comparison between the results of oxide metallurgy with Ca deoxidation and Mg deoxidation

  • Received:2016-01-22 Revised:2016-02-24 Accepted:1900-01-01 Online:2016-06-05 Published:2016-06-15

摘要: 为了提高厚板经400 kJ/cm大线能量焊接后热影响区的低温韧性,在热力学计算的基础上,研究了铝脱氧、钙脱氧和镁脱氧3种脱氧工艺对夹杂物的影响。利用夹杂物自动分析仪对夹杂物进行分析后发现,铝脱氧工艺析出的夹杂物尺寸大、数量少,且主要为Al2O3和Al2O3+CaO的复合夹杂物;钙脱氧工艺析出夹杂物的主要类型为3μm以下小尺寸的表面包裹MnS铝酸钙夹杂。镁脱氧工艺生成了大量1μm左右弥散分布的MgO和以MgO为核心的表面有TiN和MnS析出的夹杂物。利用钙脱氧和镁脱氧工艺生产的钢板经过400kJ/cm大线能量焊接热模拟后热影响区的-20℃冲击功都在180J以上。

关键词: 氧化物冶金, 大线能量焊接, 低温韧性, 夹杂物。

Abstract: To improve the low-temperature toughness of heat-affected zone(HAZ) of heavy plates, the inclusions of deoxidation with aluminum calcium magnesium were studied on the basis of thermodynamic calculation by Inclusions Automatic Analyzer System. The results showed that the inclusions with aluminum deoxidation were large size and low density and the main types of inclusions were Al2O3 and calcium aluminate. The main types of inclusions with calcium deoxidation were calcium aluminate parcelled MnS which size was below 3μm. The main types of inclusions with magnesium deoxidation was MgO and MgO which surfaced precipitation of TiN or MnS, and the sizes were below 1μm. After simulating welding test with heat input of 400 kJ/cm, the impact energy value at -20 ℃ on HAZ of specimen with magnesium deoxidation and calcium deoxidation reached more than 180 J.

Key words: oxide metallurgy, high heat input welding, low-temperature toughness, inclusion.