›› 2016, Vol. 32 ›› Issue (1): 6-11.

• 钢水冶炼 • 上一篇    下一篇

转炉留渣双渣工艺脱磷阶段成渣路线研究

李翔1,包燕平2,王敏3,林路4   

  1. 1. 北京科技大学
    2. 北京科技大学冶金与生态工程学院
    3.
    4. 北京科技大学冶金工程研究院
  • 收稿日期:2015-06-24 修回日期:2015-09-15 接受日期:1900-01-01 出版日期:2016-02-05 发布日期:2016-02-29
  • 通讯作者: 李翔 E-mail:lixiang8656@163.com
  • 基金资助:
    国家自然科学基金资助项目

Study on slag forming route of dephosphorization stage during conventer slag-remaning and double slag process

  • Received:2015-06-24 Revised:2015-09-15 Accepted:1900-01-01 Online:2016-02-05 Published:2016-02-29

摘要: 从优化留渣-双渣工艺脱磷效果的角度,通过热力学经验公式计算了:碱度、FeO、MgO、MnO含量对lg LP(LP磷在渣-钢中平衡分配比)的影响,确定脱磷阶段理论渣系控制范围是:R=1.5~2.5,w(FeO)=15%~25%,w(MgO)<8%,w(MnO)<10%。使用Factsage热力学软件计算得到了CaO-SiO2-FeO-MnO-MgO 五元渣系液相线图,综合经验公式及液相线图计算结果,设计了一条留渣双渣工艺脱磷阶段理论计算成渣路线。该成渣路线的特点是:FeO含量高,碱度变化趋势为先由高到低,然后缓慢增加。生产实践表明,采用该成渣路线,转炉渣料消耗下降了22.7%,同时转炉冶炼终点脱磷率为92.2%,达到了降低渣料消耗与高效脱磷的双重目的。

关键词: 留渣双渣, 脱磷, 成渣路线

Abstract: In order to improve the dephosphorization effect during slag-remaning and double slag process,the influence of slag basicity and FeO,MgO and MnO content on lg LP(LP is the equilibrium distribution ratio of phosphorus in slag- steel)were calculated by thermodynamic empirical formula. The results indicate that the theoretical composition range of slag during dephosphorization process is that slag basicity is about 1.5~2.5, w(FeO)=15%~25%,w(MgO)<8%,w(MnO)<10%. Liquidus diagram of CaO-SiO2-FeO-MnO-MgO slag systems was calculated by thermodynamic software Factsage. Theoretical calculate slag forming route was designed for dephosphorization stage during slag-remaining and double slag process with the comprehensive consideration of empirical formula and liquidus diagram calculate results. The characteristics of the slag forming route is that FeO content is high and the slag basicity changes from high to low and then increases slowly. The production practice results indicate that the consumption of slag material decreased by 22.7% and dephosphorization rate reached 92.2% at the end of converter steelmaking with this slag forming route. The experiment achieved the dual goals of decreasing slag material consumption and efficient dephosphorization.

Key words: Slag-remaining and double slag process, dephosphorization, slag forming route