炼钢

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复吹转炉双渣法脱磷冶炼工艺一次倒炉温度最优化选择

  

  1. (钢铁研究总院 冶金工艺研究所,北京100081)
  • 接受日期:1900-01-01 出版日期:2015-08-05

Optimal choice of the first turndown temperature of BOFdouble slag dephosphorization process

  • Accepted:1900-01-01 Online:2015-08-05

摘要: 从碳-磷选择性氧化、脱磷反应平衡、转炉熔池磷分配比与脱磷渣熔点的角度分析了复吹转炉双渣法冶炼工艺一次倒炉温度的选择。提出一次倒炉温度最佳控制范围为1 350~1 400 ℃,并进行了工业试验,结果表明:将一次倒炉温度控制在1 350~1 400 ℃,一次倒炉平均脱磷率、脱磷渣平均w(P2O5)分别达到63.11 %、3.10 %。并对1 350~1 400 ℃区间内试验炉次一次倒炉熔渣碱度、氧化性与一次倒炉脱磷效果的关系做了进一步研究,发现:碱度为1.8~2.0、w(T.Fe)=14 %~17 %的脱磷渣系更有利于获得一次倒炉的最佳脱磷效果。

关键词: 双渣, 脱磷, 一次倒炉温度, 脱磷率, 磷分配比

Abstract: The first turndown temperature of BOF double slag melting process was discussed, from the point of the selective oxidation of phosphorus and carbon, the equilibrium of the dephosphorization reaction, the distribution ratio of phosphorus in BOF bath, and the melting point of the dephosphorization slag. The temperature region from 1 350 ℃ to 1 400 ℃ was proposed as the optimal choice in this article, and trial experiments were also taken into action, the results of the first turndown show that, the average dephosphorization ratio of 63.11 % and the average P2O5 mass fraction of the dephosphorization slag of 3.1 % were got, while the first turndown temperature were located in the region from 1 350 ℃ to 1 400 ℃. And further investigation about the influence made by the slag basicity and oxidbillity were also made under the circumstance of the first turndown temperature was controlled in the region from 1 350 ℃ to 1 400 ℃, which revealed that the basicity of 1.8to 2.0 and the oxidbillity of 14 % to 17 % make more contribution to the acquisition of the optimal dephosphorization results of the first turndown point.

Key words: double slag, dephosphorization, first turndown temperature, dephosphorization rate, distribution ratio of phosphorous