炼钢 ›› 2014, Vol. 30 ›› Issue (6): 42-45.

• 试验研究 • 上一篇    下一篇

脱氧制度对H08C焊丝钢连铸水口结瘤的影响

  

  1. (1.江苏省(沙钢)钢铁研究院,江苏 张家港 215625;2.达力普石油专用管有限公司,河北 沧州 061000)
  • 接受日期:1900-01-01 出版日期:2014-12-05

Effect of deoxidation schema on SEN clogging for H08C welding wire steel

  • Accepted:1900-01-01 Online:2014-12-05

摘要: 采用两种脱氧制度试制了H08C焊丝钢,方案1为先采用硅、锰预脱氧,再用钛进行终脱氧;方案2为先采用铝深脱氧,再进行钛合金化。用扫描电镜(SEM/EDS)分析了不同脱氧制度下钢液中夹杂物的形貌、成分以及连铸水口结瘤物的组成,采用电解的方法提取了钢中夹杂物并进行了定量分析。结果表明:精炼结束后,两种脱氧制度钢液中夹杂物的类型相同,都为MnO-Al2O3-SiO2-TiOx、MgO-Al2O3-TiOx夹杂物,方案1钢液中w(TiOx)=0.003 3 %,方案2钢液中w(TiOx)=0.000 8 %;两种方案结瘤物中的非金属相组成与钢液中的夹杂物成分相同,但方案1的结瘤物中含有较多的金属相,而方案2基本不含金属相。采用方案2的脱氧制度有利于改善连铸过程中水口的结瘤问题。

关键词: 焊丝钢, 脱氧, 水口结瘤, 夹杂物

Abstract: H08C welding wire steel was produced using two deoxidation schemas, one schema is using siliconmanganese to predeoxidize the steel, afterward using ferrotitanium deeply deoxidize the steel; the other one is adding aluminum to deeply deoxidize the steel, then proceeding titanium alloying. The morphology and chemical composition of inclusions in liquid steel and clogs on the submerged entry nozzle were characterized by SEM/EDS,inclusions in liquid steel samples were extracted by sampleelectrolysis method and were quantitatively characterized. The results indicates the inclusion type at LF end is the same for the two deoxidation schemas, which is MnO-Al2O3-SiO2-TiOx, MgO-Al2O3-TiOx, the mass fraction of TiOx inclusion for the first schema is 0.003 3 % in molten steel, and 0.000 8 % for the second schema. The compositions of nonmetallic phase in clogs are the same as the inclusion compositions in liquid steel respectively for both of the two schemas, but there is much iron bulk in the clogs for the first schema, and almost no iron bulk for the second schema. The second deoxidation schema is beneficial to the castability of liquid steel.

Key words: welding wire steel, deoxidation, SEN clogging, inclusion